Amphiphilic polymeric micelles as microreactors: improving the photocatalytic hydrogen production of the [FeFe]-hydrogenase mimic in water.

نویسندگان

  • Feng Wang
  • Min Wen
  • Ke Feng
  • Wen-Jing Liang
  • Xu-Bing Li
  • Bin Chen
  • Chen-Ho Tung
  • Li-Zhu Wu
چکیده

An amphiphilic polymeric micelle is utilized as a microreactor to load a hydrophobic [FeFe]-hydrogenase mimic in water. The local concentration enhancement and strong interaction between the mimic and the photosensitizer as well as the water-mediated fast proton migration caused by the microreactor improve photocatalytic hydrogen production remarkably in water.

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عنوان ژورنال:
  • Chemical communications

دوره 52 3  شماره 

صفحات  -

تاریخ انتشار 2016